Lithographic apparatus and device manufacturing method

ABSTRACT

An immersion lithographic apparatus is provided with a liquid confinement structure which defines at least in part a space configured to contain liquid between the projection system and the substrate. In order to reduce the crossing of the edge of the substrate which is being imaged (which can lead to inclusion of bubbles in the immersion liquid), the cross-sectional area of the space in a plane parallel to the substrate is made as small as possible. The smallest theoretical size is the size of the target portion which is imaged by the projection system. In an embodiment, the shape of a final element of the projection system is also changed to have a similar size and/or shape in a cross-section parallel to the substrate to that of the target portion.

This application is a continuation of co-pending U.S. patent application Ser. No. 14/871,795, filed Sep. 30, 2015, which is a continuation application of U.S. patent application Ser. No. 14/484,076, filed Sep. 11, 2014, now U.S. Pat. No. 9,477,153, which is a continuation application of U.S. patent application Ser. No. 13/589,841, filed Aug. 20, 2012, now U.S. Pat. No. 8,860,924, which is a continuation application of U.S. patent application Ser. No. 11/120,186, filed May 3, 2005, now U.S. Pat. No. 8,248,577, the contents of each of the foregoing applications is hereby incorporated in its entirety by reference.

FIELD

The invention relates to a lithographic apparatus and a method for manufacturing a device.

BACKGROUND

A lithographic apparatus is a machine that applies a desired pattern onto a substrate, usually onto a target portion of the substrate. A lithographic apparatus can be used, for example, in the manufacture of integrated circuits (ICs). In that instance, a patterning device, which is alternatively referred to as a mask or a reticle, may be used to generate a circuit pattern to be formed on an individual layer of the IC. This pattern can be transferred onto a target portion (e.g. comprising part of, one, or several dies) on a substrate (e.g. a silicon wafer). Transfer of the pattern is typically via imaging onto a layer of radiation-sensitive material (resist) provided on the substrate. In general, a single substrate will contain a network of adjacent target portions that are successively patterned. Known lithographic apparatus include so-called steppers, in which each target portion is irradiated by exposing an entire pattern onto the target portion at one time, and so-called scanners, in which each target portion is irradiated by scanning the pattern through a radiation beam in a given direction (the “scanning”-direction) while synchronously scanning the substrate parallel or anti-parallel to this direction. It is also possible to transfer the pattern from the patterning device to the substrate by imprinting the pattern onto the substrate

It has been proposed to immerse the substrate in the lithographic projection apparatus in a liquid having a relatively high refractive index, e.g. water, so as to fill a space between the final element (e.g., a lens, another optical element, or other structure) of the projection system and the substrate. The point of this is to enable imaging of smaller features since the exposure radiation will have a shorter wavelength in the liquid. (The effect of the liquid may also be regarded as increasing the effective NA of the system and also increasing the depth of focus.) Other immersion liquids have been proposed, including water with solid particles (e.g. quartz) suspended therein.

However, submersing the substrate or substrate and substrate table in a bath of liquid (see, for example, U.S. Pat. No. 4,509,852, hereby incorporated in its entirety by reference) means that there is a large body of liquid that must be accelerated during a scanning exposure. This requires additional or more powerful motors and turbulence in the liquid may lead to undesirable and unpredictable effects.

One of the solutions proposed is for a liquid supply system to provide liquid on only a localized area of the substrate and in between the final element of the projection system and the substrate using a liquid confinement system (the substrate generally has a larger surface area than the final element of the projection system). One way which has been proposed to arrange for this is disclosed in PCT patent application publication no. WO 99/49504, hereby incorporated in its entirety by reference. As illustrated in FIGS. 2 and 3, liquid is supplied by at least one inlet IN onto the substrate, preferably along the direction of movement of the substrate relative to the final element, and is removed by at least one outlet OUT after having passed under the projection system. That is, as the substrate is scanned beneath the element in a −X direction, liquid is supplied at the +X side of the element and taken up at the −X side. FIG. 2 shows the arrangement schematically in which liquid is supplied via inlet IN and is taken up on the other side of the element by outlet OUT which is connected to a low pressure source. In the illustration of FIG. 2 the liquid is supplied along the direction of movement of the substrate relative to the final element, though this does not need to be the case. Various orientations and numbers of in- and out-lets positioned around the final element are possible, one example is illustrated in FIG. 3 in which four sets of an inlet with an outlet on either side are provided in a regular pattern around the final element.

SUMMARY

The presence of bubbles in the immersion liquid of an immersion lithography apparatus may deleteriously affect the imaging quality and evaporation of immersion liquid from the substrate which can lead to overlay errors, problems with focus control and drying stains.

Accordingly, it would be advantageous, for example, to reduce bubble formation in and evaporation of the immersion liquid.

According to an aspect of the invention, there is provided a lithographic apparatus comprising:

a substrate table constructed to hold a substrate; and

a projection system configured to project a patterned radiation beam onto a target portion of the substrate and having an element immediately adjacent the substrate, the element having a cross-sectional shape in a plane substantially parallel to the substrate which is rectilinear.

According to an aspect of the invention, there is provided a lithographic apparatus, comprising:

a substrate table constructed to hold a substrate;

a projection system configured to project a patterned radiation beam onto a target portion of the substrate; and

a liquid confinement structure having a surface defining at least in part a space configured to contain liquid between the projection system and the substrate, wherein in a plane substantially parallel to the substrate, at a position closest to the substrate, the space has a cross-section which substantially conforms in shape, area, or both to that of the target portion.

According to an aspect of the invention, there is provided a lithographic apparatus, comprising:

a substrate table constructed to hold a substrate;

a projection system configured to project a patterned radiation beam onto a target portion of the substrate; and

a liquid confinement structure having a surface defining at least in part a space configured to contain liquid between the substrate and an element of the projection system immediately adjacent the substrate, wherein in a plane substantially parallel to the substrate an area, a shape, or both of the cross-section of the element, of the space, or both, substantially conform(s) to that of the target portion.

According to an aspect of the invention, there is provided a device manufacturing method comprising using a projection system to project on a target portion of a substrate a patterned beam of radiation, wherein an element of the projection system immediately adjacent the substrate has a cross-sectional shape in a plane substantially parallel to the substrate which is rectilinear.

According to an aspect of the invention, there is provided a device manufacturing method comprising using a projection system to project on a target portion of a substrate a patterned beam of radiation, wherein a space configured to be filled with liquid between the projection system and the substrate is defined at least in part by a surface of a liquid confinement structure and wherein in a plane substantially parallel to the substrate at a position closest to the substrate the space has a cross-section which substantially conforms in shape, area, or both to that of the target portion.

According to an aspect of the invention, there is provided a device manufacturing method comprising using a projection system to project on a target portion of a substrate a patterned beam of radiation, wherein a liquid is provided in a space between the projection system and the substrate and which space is defined at least in part by a surface of a liquid confinement structure and the space, an element of the projection system immediately adjacent the substrate, or both, has a cross-section in a plane substantially parallel to the substrate which conforms closely in size, shape, or both to that of the target portion.

BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the invention will now be described, by way of example only, with reference to the accompanying schematic drawings in which corresponding reference symbols indicate corresponding parts, and in which:

FIG. 1 depicts a lithographic apparatus according to an embodiment of the invention;

FIGS. 2 and 3 depict a liquid supply system for use in a lithographic projection apparatus;

FIG. 4 depicts another liquid supply system for use in a lithographic projection apparatus;

FIG. 5 depicts a further liquid supply system for use in a lithographic projection apparatus;

FIG. 6 depicts schematically in plan a space of a liquid confinement structure in accordance with an embodiment of the invention;

FIG. 7 depicts schematically in plan a space of another liquid confinement structure in accordance with an embodiment of the invention;

FIG. 8 depicts in cross-section a liquid confinement structure and a final element of the projection system according to the invention;

FIG. 9 depicts in cross-section a final element of the projection system;

FIG. 10 depicts schematically the final element of FIG. 9; and

FIG. 11 depicts a lithographic apparatus according to an embodiment of the invention.

DETAILED DESCRIPTION

FIG. 1 schematically depicts a lithographic apparatus according to one embodiment of the invention, The apparatus comprises:

-   -   an illumination system (illuminator) IL configured to condition         a radiation beam B (e.g. UV radiation or DUV radiation).     -   a support structure (e.g. a mask table) MT constructed to         support a patterning device (e.g. a mask) MA and connected to a         first positioner PM configured to accurately position the         patterning device in accordance with certain parameters;     -   a substrate table (e.g. a wafer table) WT constructed to hold a         substrate (e.g. a resist-coated wafer) W and connected to a         second positioner PW configured to accurately position the         substrate in accordance with certain parameters; and     -   a projection system (e.g. a refractive projection lens system)         PS configured to project a pattern imparted to the radiation         beam B by patterning device MA onto a target portion C (e.g.         comprising one or more dies) of the substrate W.

The illumination system may include various types of optical components, such as refractive, reflective, magnetic, electromagnetic, electrostatic or other types of optical components, or any combination thereof, for directing, shaping, or controlling radiation.

The support structure holds the patterning device in a manner that depends on the orientation of the patterning device, the design of the lithographic apparatus, and other conditions, such as for example whether or not the patterning device is held in a vacuum environment. The support structure can use mechanical, vacuum, electrostatic or other clamping techniques to hold the patterning device. The support structure may be a frame or a table, for example, which may be fixed or movable as required. The support structure may ensure that the patterning device is at a desired position, for example with respect to the projection system. Any use of the terms “reticle” or “mask” herein may be considered synonymous with the more general term “patterning device.”

The term “patterning device” used herein should be broadly interpreted as referring to any device that can be used to impart a radiation beam with a pattern in its cross-section such as to create a pattern in a target portion of the substrate. It should be noted that the pattern imparted to the radiation beam may not exactly correspond to the desired pattern in the target portion of the substrate, for example if the pattern includes phase-shifting features or so called assist features. Generally, the pattern imparted to the radiation beam will correspond to a particular functional layer in a device being created in the target portion, such as an integrated circuit.

The patterning device may be transmissive or reflective. Examples of patterning devices include masks, programmable mirror arrays, and programmable LCD panels. Masks are well known in lithography, and include mask types such as binary, alternating phase-shift, and attenuated phase-shift, as well as various hybrid mask types. An example of a programmable mirror array employs a matrix arrangement of small mirrors, each of which can be individually tilted so as to reflect an incoming radiation beam in different directions. The tilted mirrors impart a pattern in a radiation beam which is reflected by the mirror matrix.

The term “projection system” used herein should be broadly interpreted as encompassing any type of projection system, including refractive, reflective, catadioptric, magnetic, electromagnetic and electrostatic optical systems, or any combination thereof, as appropriate for the exposure radiation being used, or for other factors such as the use of an immersion liquid or the use of a vacuum. Any use of the term “projection lens” herein may be considered as synonymous with the more general term “projection system”.

As here depicted, the apparatus is of a transmissive type (e.g. employing a transmissive mask). Alternatively, the apparatus may be of a reflective type (e.g. employing a programmable mirror array of a type as referred to above, or employing a reflective mask).

The lithographic apparatus may be of a type having two (dual stage) or more substrate tables (and/or two or more mask tables). In such “multiple stage” machines the additional tables may be used in parallel, or preparatory steps may be carried out on one or more tables while one or more other tables are being used for exposure,

Referring to FIG. 1, the illuminator IL receives a radiation beam from a radiation source SO. The source and the lithographic apparatus may be separate entities, for example when the source is an excimer laser. In such cases, the source is not considered to form part of the lithographic apparatus and the radiation beam is passed from the source SO to the illuminator IL with the aid of a beam delivery system BD comprising, for example, suitable directing mirrors and/or a beam expander. In other cases the source may be an integral part of the lithographic apparatus, for example when the source is a mercury lamp. The source SO and the illuminator IL, together with the beam delivery system BD if required, may be referred to as a radiation system.

The illuminator IL may comprise an adjuster AD for adjusting the angular intensity distribution of the radiation beam. Generally, at least the outer and/or inner radial extent (commonly referred to as σ-outer and σ-inner, respectively) of the intensity distribution in a pupil plane of the illuminator can be adjusted. In addition, the illuminator IL may comprise various other components, such as an integrator IN and a condenser CO. The illuminator may be used to condition the radiation beam, to have a desired uniformity and intensity distribution in its cross-section.

The radiation beam B is incident on the patterning device (e.g., mask MA), which is held on the support structure (e.g., mask table MT), and is patterned by the patterning device. Having traversed the mask MA, the radiation beam B passes through the projection system PS, which focuses the beam onto a target portion C of the substrate W. With the aid of the second positioner PW and position sensor IF (e.g. an interferometric device, linear encoder or capacitive sensor), the substrate table WT can be moved accurately, e.g. so as to position different target portions C in the path of the radiation beam B. Similarly, the first positioner PM and another position sensor (which is not explicitly depicted in FIG. 1) can be used to accurately position the mask MA with respect to the path of the radiation beam B, e.g. after mechanical retrieval from a mask library, or during a scan. In general, movement of the mask table MT may be realized with the aid of a long-stroke module (coarse positioning) and a short-stroke module (fine positioning), which form part of the first positioner PM. Similarly, movement of the substrate table WT may be realized using a long-stroke module and a short-stroke module, which form part of the second positioner PW. In the case of a stepper (as opposed to a scanner) the mask table MT may be connected to a short-stroke actuator only, or may be fixed. Mask MA and substrate W may be aligned using mask alignment marks M1, M2 and substrate alignment marks P1, P2. Although the substrate alignment marks as illustrated occupy dedicated target portions, they may be located in spaces between target portions (these are known as scribe-lane alignment marks). Similarly, in situations in which more than one die is provided on the mask MA, the mask alignment marks may be located between the dies.

The depicted apparatus could be used in at least one of the following modes:

1. In step mode, the mask table MT and the substrate table WT are kept essentially stationary, while an entire pattern imparted to the radiation beam is projected onto a target portion C at one time (i.e. a single static exposure). The substrate table WT is then shifted in the X and/or Y direction so that a different target portion C can be exposed. In step mode, the maximum size of the exposure field limits the size of the target portion C imaged in a single static exposure.

2. In scan mode, the mask table MT and the substrate table WT are scanned synchronously while a pattern imparted to the radiation beam is projected onto a target portion C (i.e. a single dynamic exposure). The velocity and direction of the substrate table WT relative to the mask table MT may be determined by the (de)magnification and image reversal characteristics of the projection system PS. In scan mode, the maximum size of the exposure field limits the width (in the non-scanning direction) of the target portion in a single dynamic exposure, whereas the length of the scanning motion determines the height (in the scanning direction) of the target portion.

3. In another mode, the mask table MT is kept essentially stationary holding a programmable patterning device, and the substrate table WT is moved or scanned while a pattern imparted to the radiation beam is projected onto a target portion C. In this mode, generally a pulsed radiation source is employed and the programmable patterning device is updated as required after each movement of the substrate table WT or in between successive radiation pulses during a scan. This mode of operation can be readily applied to maskless lithography that utilizes programmable patterning device, such as a programmable mirror array of a type as referred to above.

Combinations and/or variations on the above described modes of use or entirely different modes of use may also be employed.

A further immersion lithography solution with a localized liquid supply system is shown in FIG. 4. Liquid is supplied by two groove inlets IN on either side of the projection system PL and is removed by a plurality of discrete outlets OUT arranged radially outwardly of the inlets IN. The inlets IN and OUT can be arranged in a plate with a hole in its center and through which the projection beam is projected. Liquid is supplied by one groove inlet IN on one side of the projection system PL and removed by a plurality of discrete outlets OUT on the other side of the projection system PL, causing a flow of a thin film of liquid between the projection system PL and the substrate W. The choice of which combination of inlet IN and outlets OUT to use can depend on the direction of movement of the substrate W (the other combination of inlet IN and outlets OUT being inactive).

Another immersion lithography solution with a localized liquid supply system solution which has been proposed is to provide the liquid supply system with a liquid confinement structure which extends along at least a part of a boundary of the space between the final element of the projection system and the substrate table. Such a solution is illustrated in FIG. 5. The liquid confinement structure is substantially stationary relative to the projection system in the XY plane though there may be some relative movement in the Z direction (in the direction of the optical axis). In an embodiment, a seal is formed between the liquid confinement structure and the surface of the substrate. In an embodiment, the seal is a contactless seal such as a gas seal. Such a system is disclosed in U.S. patent application publication No. U.S. 2004-0207824 and European patent application publication no. EP 1420298, each hereby incorporated in its entirety by reference, and illustrated in FIG. 5.

The size and shape of the target portion C (which is sometimes referred to as the slit size) can be determined by the illumination optics, such as a quartz rod which is a light mixer and/or a masking unit which is positioned near to the exit of this rod

Bubbles may be formed in the immersion liquid due to movement of the substrate W and substrate table WT beneath the projection system PL and the substantially stationary liquid confinement system such as that illustrated in FIG. 4 or FIG. 5. In particular, when an edge of the substrate W passes under the space occupied by immersion liquid 11, bubbles may be formed in the immersion liquid and thereby reduce the imaging quality of the apparatus

Liquid confinement systems have been typically designed for use with conventional projection systems PL. In such systems, the last element tends to have a circular cross-section in a plane substantially perpendicular to the optical axis of the projection system (which is the same as a plane substantially parallel to the substrate W). In order for the liquid confinement systems to operate, the cross-sectional area of the space filled with liquid closely conforms to the shape of the final element of the projection system in one and the same plane. This is designed to be the case to maximize the available space for the liquid supply system which requires many components in a small volume. Several different designs of liquid confinement system have been proposed. One or more embodiments of the invention are applicable to all of those different designs including but not limited to those disclosed in U.S. patent publication no. U.S. 2004-0263809, PCT patent application publication no. WO 2004-090634, European patent application publication nos. EP 1420298, EP 1494079, and EP 1477856, and U.S. patent application Ser. No. 11/098,615, filed 5 Apr. 2005, the contents of each of which are incorporated in their entirety herein by reference

The liquid confinement structure illustrated in FIG. 5 is now described in detail. However, one or more embodiments of the invention are not limited in application to this type of liquid confinement structure

FIG. 5 shows a liquid reservoir or space 10 between the projection system and the substrate stage. The space 10 is filled with a liquid 11 having a relatively high refractive index, e.g. water, provided via inlet/outlet ducts 13. The liquid has the effect that the radiation of the projection beam has a shorter wavelength in the liquid than in air or a vacuum, allowing smaller features to be resolved. It is well known that the resolution limit of a projection system is determined, inter alia, by the wavelength of the projection beam and the numerical aperture of the system. The presence of the liquid may also be regarded as increasing the effective numerical aperture. Furthermore, at fixed numerical aperture, the liquid is effective to increase the depth of field

A contactless seal to the substrate around the image field of the projection system is formal so that liquid is confined in the space 10 between the substrate surface and the final element of the projection system. The space is formed or defined by a liquid confinement structure 12 positioned below and surrounding the final element of the projection system PL. Liquid is brought into the space 10 below the projection system and within the liquid confinement structure 12. The liquid confinement structure 12 extends a little above the final element of the projection system and the liquid level rises above the final element so that a buffer of liquid is provided. The liquid confinement structure 12 has an inner periphery that at the upper end, in an embodiment, closely conforms to the step of the projection system or the final element thereof and may, e.g., be round

The liquid is confined in the space 10 by a gas seal 16 between the bottom of the liquid confinement structure 12 and the surface of the substrate W. The gas seal is formed by gas, e.g. air, synthetic air, N₂ or an inert gas, provided under pressure via inlet 15 to the gap between liquid confinement structure 12 and substrate and extracted via first outlet 14. The overpressure on the gas inlet 15, vacuum level on the first outlet 14 and geometry of the gap are arranged so that there is a high-velocity gas flow inwards that confines the liquid

Other types of liquid confinement structure 12 may be used. For example, the gas seal may be replaced by a combination of a single phase extractor, a recess and a gas knife as is described in U.S. patent application Ser. No. 11/098,615, filed 5 Apr. 2005, hereby incorporated in its entirety by reference herein. Alternatively, a gas seal may be replaced by a hydrostatic or hydrodynamic bearing as is described in U.S. patent application publication No. U.S. 2005-018155, each of which are hereby incorporated in their entirety by reference

In order to reduce or minimize the amount of time which the space 10 occupied by liquid spends over an edge of the substrate W during scanning and to reduce or minimize the area of the top surface of the substrate from which immersion liquid may evaporate, the cross-section of the space 10 in a plane parallel to the top surface of the substrate W at a position closest to the substrate, is fashioned to conform closely to the shape of the target portion TP (sometimes referred to as the illumination slit area). This is illustrated in FIG. 6. As can be seen from FIG. 6, which is an illustration of the liquid confinement structure 12 in plan, the space 10 is defined by walls 20 extending between a lower opening 40 of the space 10 in the lower surface of the liquid confinement structure 12 and an upper opening 60 in the upper surface of the liquid confinement structure 12. In FIG. 6, the upper opening 60 is circular such that the liquid confinement structure 12 may be used with a conventional projection system PL in which the final element of the projection system is radially symmetric and the bottom opening 40 which is closest to the substrate W is rectangular and conforms in shape closely to the shape of the target portion TP. Furthermore, the lower opening 40 also closely conforms in size to that of the target portion TP though of course it cannot be smaller than the target portion TP. In an embodiment, the area of the lower opening 40 or of the cross-section of the space in a plane substantially parallel to the substrate W at a position closest to the substrate W is less than 1.5 times the area of the target portion TP, in an embodiment less than 1.4, 1.3, 1.2 or 1,1 times the area of the target portion TP. This difference is to account for relative movement of the liquid supply system to the final element either in the case of ‘play’ or so that the movement can be deliberately carried out

The surface 20 of the liquid confinement structure 12 which defines the space 10 in which the liquid is confined is shaped to transfer smoothly from the shape of the upper opening 60 to the lower opening 40 and accommodates the shape of the final element of the projection system and allows some relative movement of the confinement system as is described in European patent application publication no. EP 1477856, the contents of which is hereby incorporated in its entirety by reference. However, such a transfer can result in difficulties in the flow conditions and so, in an embodiment, the shapes of the upper and lower openings, 40, 60 are similar, at least both rectilinear, This is particularly easy to arrange for if the projection system is close to the substrate, The further the projection system is from the substrate the more circular the projection system bottom needs to be because of the greater angles (there tend to be more pupil shapes). A rectilinear situation is illustrated in FIG. 7 in which the upper opening 60 is square and the lower opening 40 is rectangular. In this arrangement, it should be easy to achieve parallel flow of immersion liquid across the target portion TP without re-circulation of immersion liquid. Re-circulation of immersion liquid is to be avoided because re-circulated immersion liquid may be heated up by the projection beam PB more than non- re-circulated immersion liquid and the variation in temperature can lead to variations in refractive index of the immersion liquid in the space

If the size of the lower opening 40 of the space in the liquid confinement structure 12 is reduced or minimized as is illustrated in FIGS. 6 and 7 by making its cross-sectional shape and/or size conform closely or be similar to that of the target portion TP, during scanning of a whole substrate W the number of scans in which the opening 40 passes over an edge of the substrate is greatly reduced. Thus, the opportunity for bubble formation in the immersion liquid in the space 10 due to passing over of the edge of the substrate is reduced and so is the area from which immersion liquid can evaporate

FIGS. 8-10 illustrate an embodiment of the invention in which both the final element of the projection system and the liquid confinement structure 12 are optimized in shape and geometry so that the size of the lower opening 40 can be made to closely conform to the shape and/or size of the target portion TP without deleteriously affecting other operating conditions such as the ability to generate parallel flow of immersion liquid across the target portion TP or reducing the available volume for the liquid supply system. Indeed, this embodiment may increase available volume for the liquid supply system over prior systems

In FIG. 8, a liquid confinement structure 12 similar to that illustrated in FIG. 7 is used. Thus, the lower opening 40 of the space is of a similar shape and dimension to the target portion TP in a plane PL₂ which is substantially parallel to the substrate W and adjacent the substrate W, e.g., at a position closest to the substrate W. As is illustrated, the liquid confinement structure 12 partly surrounds the final element of the projection system PL. Thus, a plane PL₁ exists which is substantially parallel to the plane of the top surface of the substrate W and also intersects both the space 10 defined by the liquid confinement structure 12 and the lower end of the final element of the projection system PL. In this plane, the cross-sectional shape and size of the space is similar to that of the cross-sectional shape and size of the final element of the projection system PL. Thus, in contrast to the final element of the projection system which would be used with the liquid confinement structure 12 of FIG. 6, the final element of the projection system PL is shaped such that it also has a rectangular or square cross-section in that plane so that it is possible for the inner surface of the liquid confinement structure 12 which defines the space to transfer in shape from the lower opening 40 to the upper opening 60 without needing to convert straight lines to curved lines. This helps in the establishment of parallel flow of immersion liquid across the target portion TP and simplifies the shaping of walls 20. As the distance between the projection system and the substrate increases, the importance of a homogeneous immersion liquid increases so that parallel flow is even more desirable. The walls 20 are all substantially flat. In an embodiment, the shape of the lower opening and upper opening, and thereby the shape of the cross-section of the final element of the projection system PL, are similar to the shape of the target portion

In FIG. 8, a space 10 is illustrated which has a cross-section in a plane substantially parallel to the substrate W which decreases as the substrate W is approached. This need not necessarily be the case and it may be that the upper and lower openings 40, 60 are the same or substantially the same size so that the side walls of the space defined by the liquid confinement structure 12 are parallel in cross-section, As is illustrated in FIG. 8, the rate of increase/decrease in cross-sectional area as the substrate W is left/approached is not necessarily constant and a space 10 with two gradients of inner side wall 20 is provided, a steep gradient between the substrate 20 and substantially the bottom of the projection system and another shallower gradient above that

FIG. 9 illustrates a final element of the projection system. The dotted lines show the shape of a typical final element of a projection system and it can be seen that those parts of the final element can be removed without affecting the optical properties of the final element in use. Machining away the areas shown in dotted lines is one way of manufacturing such an element. Thus, the bottom surface of the final element is a shape to which the space of the liquid confinement structure 12 can be closely formed without the need to use a curved upper opening 60. The very bottom of the final element is illustrated as having a coating 100 applied to it (or a quartz plate or so-called abslussplatte 100). The coating or quartz plate 100 is shown as being flat. However, this need not be the case and the very bottom surface of the final element may be curved and may or may not have a coating or quartz plate applied to it

FIG. 10 is a three dimensional illustration of the final element of the projection system in which the transition from a curved upper surface to a non- curved lower surface is clearly seen. The top half of the element is normally shaped and it is the bottom half of the element which has flat sides joined by straight edges 70 i.e. has a rectilinear cross-sectional shape in a plane substantially parallel to the substrate W

An embodiment of the invention is also applicable to off axis projection systems in which the projection beam is arranged such that the target portion is not, in plan, centered under the middle of the projection system. An example embodiment of this arrangement is depicted in FIG. 11.

In European patent application publication no. EP 1420300 and United States patent application publication no. U.S. 2004-0136494, each hereby incorporated in their entirety by reference, the idea of a twin or dual stage immersion lithography apparatus is disclosed. Such an apparatus is provided with two tables for supporting a substrate. Leveling measurements are carried out with a table at a first position, without immersion liquid, and exposure is carried out with a table at a second position, where immersion liquid is present. Alternatively, the apparatus has only one table.

In an embodiment, there is provided a lithographic apparatus comprising: a substrate table constructed to hold a substrate; and a projection system configured to project a patterned radiation beam onto a target portion of the substrate and having an element immediately adjacent the substrate, the element having a cross-sectional shape in a plane substantially parallel to the substrate which is rectilinear.

In an embodiment, the cross-sectional shape is similar to the shape of the target portion. In an embodiment, a bottom surface closest to the substrate of the element is curved. In an embodiment, the target portion is substantially rectangular. In an embodiment, the cross-sectional shape of the element in a plane substantially parallel to the substrate has an area which is less than 1.5 times the area of the target portion. In an embodiment, the apparatus further comprises a liquid confinement structure having a surface at least in part defining a space configured to contain a liquid between the projection system and the substrate, wherein in a plane substantially parallel to the substrate the space has a cross-section which substantially conforms in shape to the shape of the target portion. In an embodiment, the cross-section of the space has an area which is less than 1.5 times the area of the target portion. In an embodiment, the surface of the liquid confinement structure extends beyond a bottom surface closest to the substrate of the element, and, in a plane which intersects both the space and the element and which is substantially parallel to the substrate, the cross-sectional shapes and areas of the space and element closely conform.

In an embodiment, there is provided a lithographic apparatus, comprising: a substrate table constructed to hold a substrate; a projection system configured to project a patterned radiation beam onto a target portion of the substrate; and a liquid confinement structure having a surface at least in part defining a space configured to contain liquid between the projection system and the substrate, wherein in a plane substantially parallel to the substrate, at a position closest to the substrate, the space has a cross-section which substantially conforms in shape, area, or both to that of the target portion.

In an embodiment, the cross-section of the space has an area which is less than 1.5 times the area of the target portion. In an embodiment, in a plane substantially parallel to the substrate and which intersects both the space and a final element of the projection system, the periphery of the cross-section of the final element is substantially evenly surrounded by the periphery of the cross-section of the space. In an embodiment, a final element of the projection system has a cross-section in a plane substantially parallel to the substrate which substantially conforms in shape to the shape of the target portion, the cross-section of the space, or both. In an embodiment, the target portion is substantially rectangular.

In an embodiment, there is provided a lithographic apparatus, comprising: a substrate table constructed to hold a substrate; a projection system configured to project a patterned radiation beam onto a target portion of the substrate; and a liquid confinement structure having a surface at least in part defining a space configured to contain liquid between the substrate and an element of the projection system immediately adjacent the substrate, wherein in a plane substantially parallel to the substrate an area, a shape, or both of the cross-section of the element, of the space, or both, substantially conform(s) to that of the target portion.

In an embodiment, the space is tapered such that the cross-sectional area of the space in a plane substantially parallel to the substrate reduces as the substrate is approached. In an embodiment, the cross-sectional shape of the space in a plane substantially parallel to the substrate changes from a position furthest from the substrate to a position closest to the substrate, wherein at the position closest to the substrate the cross-sectional shape is substantially the same as the shape of the target portion,

In an embodiment, there is provided a device manufacturing method comprising using a projection system to project on a target portion of a substrate a patterned beam of radiation, wherein an element of the projection system immediately adjacent the substrate has a cross-sectional shape in a plane substantially parallel to the substrate which is rectilinear.

In an embodiment, there is provided a device manufacturing method comprising using a projection system to project on a target portion of a substrate a patterned beam of radiation, wherein a space configured to be filled with liquid between the projection system and the substrate is defined at least in part by a surface of a liquid confinement structure and wherein in a plane substantially parallel to the substrate at a position closest to the substrate the space has a cross-section which substantially conforms in shape, area, or both to that of the target portion.

In an embodiment, there is provided a device manufacturing method comprising using a projection system to project on a target portion of a substrate a patterned beam of radiation, wherein a liquid is provided in a space between the projection system and the substrate and which space is defined at least in part by a surface of a liquid confinement structure and the space, an element of the projection system immediately adjacent the substrate, or both, has a cross-section in a plane substantially parallel to the substrate which conforms closely in size, shape, or both to that of the target portion.

Although specific reference may be made in this text to the use of lithographic apparatus in the manufacture of ICs, it should be understood that the lithographic apparatus described herein may have other applications, such as the manufacture of integrated optical systems, guidance and detection patterns for magnetic domain memories, flat-panel displays, liquid-crystal displays (LCDs), thin-film magnetic heads, etc. The skilled artisan will appreciate that, in the context of such alternative applications, any use of the terms “wafer” or “die” herein may be considered as synonymous with the more general terms “substrate” or “target portion”, respectively. The substrate referred to herein may be processed, before or after exposure, in for example a track (a tool that typically applies a layer of resist to a substrate and develops the exposed resist), a metrology tool and/or an inspection tool. Where applicable, the disclosure herein may be applied to such and other substrate processing tools. Further, the substrate may be processed more than once, for example in order to create a multi-layer IC, so that the term substrate used herein may also refer to a substrate that already contains multiple processed layers,

Although specific reference may have been made above to the use of embodiments of the invention in the context of optical lithography, it will be appreciated that the invention may be used in other applications, for example imprint lithography, and where the context allows, is not limited to optical lithography. In imprint lithography topography in a patterning device defines the pattern created on a substrate. The topography of the patterning device may be pressed into a layer of resist supplied to the substrate whereupon the resist is cured by applying electromagnetic radiation, heat, pressure or a combination thereof. The patterning device is moved out of the resist leaving a pattern in it after the resist is cured,

The terms “radiation” and “beam” used herein encompass all types of electromagnetic radiation, including ultraviolet (UV) radiation (e.g. having a wavelength of or about 365, 248, 193, 157 or 126 nm) and extreme ultra-violet (EUV) radiation (e.g. having a wavelength in the range of 5-20 nm), as well as particle beams, such as ion beams or electron beams.

The term “lens”, where the context allows, may refer to any one or combination of various types of optical components, including refractive, reflective, magnetic, electromagnetic and electrostatic optical components.

While specific embodiments of the invention have been described above, it will be appreciated that the invention may be practiced otherwise than as described. For example, the invention may take the form of a computer program containing one or more sequences of machine-readable instructions describing a method as disclosed above, or a data storage medium (e.g. semiconductor memory, magnetic or optical disk) having such a computer program stored therein.

One or more embodiments of the invention may be applied to any immersion lithography apparatus, in particular, but not exclusively, those types mentioned above and whether the immersion liquid is provided in the form of a bath or only on a localized surface area of the substrate. A liquid supply system as contemplated herein should be broadly construed. In certain embodiments, it may be a mechanism or combination of structures that provides a liquid to a space between the projection system and the substrate and/or substrate table. It may comprise a combination of one or more structures, one or more liquid inlets, one or more gas inlets, one or more gas outlets, and/or one or more liquid outlets that provide liquid to the space. In an embodiment, a surface of the space may be a portion of the substrate and/or substrate table, or a surface of the space may completely cover a surface of the substrate and/or substrate table, or the space may envelop the substrate and/or substrate table. The liquid supply system may optionally further include one or more elements to control the position, quantity, quality, shape, flow rate or any other features of the liquid.

The descriptions above are intended to be illustrative, not limiting. Thus, it will be apparent to one skilled in the art that modifications may be made to the invention as described without departing from the scope of the claims set out below. 

The invention claimed is:
 1. A projection optical system which projects a reduced image of a pattern disposed on a first plane with light from the pattern onto a second plane through liquid, the projection optical system comprising: a refractive optical element having a light emitting surface, through a part of which the light passes in use, the light emitting surface being arranged so as to contact the liquid which is disposed in an optical path of the light from the light emitting surface in use, wherein the projection optical system projects the reduced image in a projection region on the second plane, a center of the projection region being decentered from an optical axis of the projection optical system with respect to one of a first direction and a second direction which are perpendicular to each other and are perpendicular to the optical axis; wherein the refractive optical element has a protruding portion formed in a second plane side of the refractive optical element so as to protrude toward the second plane with respect to a different portion of the refractive optical element from the protruding portion; and wherein the protruding portion is formed so that a center of the light emitting surface is decentered from the optical axis with respect to the one of the first and second directions.
 2. The projection optical system according to claim 1, wherein the protruding portion has a tilted surface that is tilted to the light emitting surface and extends from the light emitting surface toward a first plane side.
 3. The projection optical system according to claim 2, wherein the tilted surface of the protruding portion is formed so that as the tilted surface comes closer to the light emitting surface, a width of the protruding portion becomes narrower with respect to the one of the first and second directions.
 4. The projection optical system according to claim 1, comprising a peripheral region located around the protruding portion so as to face the second plane.
 5. The projection optical system according to claim 1, wherein the light emitting surface is substantially planar and is substantially perpendicular to the optical axis.
 6. The projection optical system according to claim 1, wherein the refractive optical element has a light entering surface through which the light enters into the refractive optical element, the light entering surface being convex toward the first plane.
 7. The projection optical system according to claim 6, wherein the protruding portion is formed so that the center of the light emitting surface is substantially centered with the center of the light entering surface with respect to the other of the first and second directions.
 8. The projection optical system according to claim 1, wherein the protruding portion is shaped to be substantially symmetrical with respect to an axis parallel to the one of the first and second directions.
 9. The projection optical system according to claim 1, wherein the center of the projection region and the center of the light emitting surface are located at a substantially same position with respect to the one of the first and second directions.
 10. The projection optical system according to claim 1, wherein a width of the light emitting surface in a direction perpendicular to the optical axis is different from a width of the light emitting surface in another orthogonal direction perpendicular to the optical axis.
 11. The projection optical system according to claim 1, wherein a width of the projection region with respect to a direction perpendicular to the optical axis is narrower than a width of the projection region with respect to another orthogonal direction perpendicular to the optical axis.
 12. The projection optical system according to claim 1, comprising a plurality of reflective and refractive optical elements including the refractive optical element having the light emitting surface arranged so as to contact the liquid.
 13. The projection optical system according to claim 12, wherein the projection optical system is a catadioptric optical system.
 14. The projection optical system according to claim 1, wherein a numerical aperture of the projection optical system is set greater than 1 in the liquid.
 15. A device manufacturing method comprising: transferring a pattern onto a substrate by projecting the pattern with the projection optical system according to claim 1; and developing the substrate on which the pattern is transferred.
 16. An exposure apparatus which exposes a substrate to light from a pattern through liquid, the apparatus comprising: a stage which holds the substrate; and the projection optical system according to claim 1, which projects a reduced image of the pattern through the liquid onto the substrate held on the stage.
 17. The exposure apparatus according to claim 16, comprising a supply and discharge mechanism which supplies an optical path between the refractive optical element of the projection optical system and the substrate on the stage which the liquid so as to contact the light emitting surface of the refractive optical element.
 18. The exposure apparatus according to claim 16, comprising a driving system which drives the stage so that the substrate on the stage is moved relative to the light from the projection optical system via the liquid.
 19. An exposure method of exposing a substrate to light from a pattern through liquid, the method comprising: holding the substrate with a stage; and projecting a reduced image of the pattern with the projection optical system according to claim 1 through the liquid onto the substrate held on the stage.
 20. The exposure method according to claim 19, driving the stage so that the substrate on the stage is moved relative to the light from the projection optical system via the liquid.
 21. A device manufacturing method comprising: exposing a substrate by use of the exposure method according to claim 20; and developing the exposed substrate.
 22. A projection system configured to project a patterned radiation beam onto a target portion of a substrate through a liquid, the projection optical system comprising: an optical element immediately adjacent the substrate and contacting the liquid, wherein the projection system has the target portion not, in plan, centered under the middle of the projection system, wherein the bottom surface of the optical element is decentered from the optical axis of the projection system, wherein the bottom surface of the optical element protrudes towards the substrate relative to an upper portion of the optical element, and wherein a periphery of the upper portion of the optical element surrounds the bottom surface from above.
 23. The projection system according to claim 22, wherein the optical element comprises tapered side surfaces extending from the upper portion of the optical element to the bottom surface of the optical element.
 24. The projection system according to claim 22, wherein the optical element has a cross-sectional area parallel to the substrate that reduces as the substrate is approached.
 25. The projection system according to claim 22, wherein the optical element is tapered such that the cross-sectional area of the optical element in a plane substantially parallel to the substrate reduces as the substrate is approached.
 26. The projection system according to claim 22, wherein the projection system is a catadioptric, off-axis projection system.
 27. The projection system according to claim 22, wherein the projection system projects the patterned radiation beam onto the target portion with demagnification.
 28. An exposure apparatus comprising: the projection system according to claim 22 for projecting an image of a predetermined pattern onto a photosensitive substrate that is set on the second plane based on illumination light from the pattern set on the first plane; and a supply and discharge mechanism for supplying and discharging the liquid.
 29. The exposure apparatus according to claim 28, wherein the pattern is projected while changing a positional relationship of the image of the pattern and the photosensitive substrate in a scanning direction.
 30. A device manufacturing method comprising: an exposure step of projecting and exposing an image of a pattern set on the first plane onto a photosensitive substrate set on the second plane with the projection system according to claim 22; and a development step of developing the photosensitive substrate that has undergone the exposure step.
 31. The projection system according to claim 22, wherein the bottom surface has a rectilinear shape.
 32. A projection system configured to project a patterned radiation beam onto a target portion of a substrate through a liquid, the projection optical system comprising: an optical element immediately adjacent the substrate, wherein a lower surface of the optical element adjacent the substrate has a cross-sectional shape that substantially conforms in shape to the shape of the target portion, wherein the projection system is an off axis projection system that has the target portion decentered from an optical axis of the projection system, wherein the lower surface that substantially conforms in shape to the shape of the target portion is decentered from the optical axis of the projection system, and wherein a periphery of an upper portion of the optical element surrounds the lower surface from above.
 33. An exposure apparatus which exposes a substrate to light from a pattern through liquid, the exposure apparatus comprising: a stage which holds the substrate; a projection optical system which projects a reduced image of the pattern with the light onto the substrate through the liquid; and a driving system which drives the stage so that in a scanning exposure of the substrate, the substrate is moved relative to the light with respect to a first direction perpendicular to an optical axis of the projection optical system, wherein the projection optical system comprises a refractive optical element having a light emitting surface, through a part of which the light passes in use and which is arranged nearest to an imaging plane of the projection optical system to contact the liquid in use, wherein the refractive optical element has a protruding portion formed in a light emitting side of the refractive optical element so as to protrude toward the imaging plane with respect to a surrounding portion other than the protruding portion, and wherein the protruding portion is formed so that a center of the light emitting surface is decentered from the optical axis with respect to the first direction.
 34. The exposure apparatus according to claim 33, wherein the projection optical system is a catadioptric projection optical system.
 35. The exposure apparatus according to claim 33, wherein a light entering surface of the refractive optical element is a convex surface and the light emitting surface is substantially planar.
 36. The exposure apparatus according to claim 33, wherein the part is formed so that a center of the light emitting surface is decentered from a center of a light entering surface of the refractive optical element.
 37. The exposure apparatus according to claim 36, wherein the refractive optical element is arranged so that the center of the light entering surface is substantially centered with the optical axis.
 38. The exposure apparatus according to claim 36, wherein the refractive optical element is arranged so that the center of the light emitting surface and the center of the light entering surface are located at a substantially same position with respect to a second direction perpendicular to the first direction and the optical axis.
 39. The exposure apparatus according to claim 38, wherein the refractive optical element is arranged so that the center of the light entering surface is substantially centered with the optical axis with respect to the second direction.
 40. The exposure apparatus according to claim 33, wherein a center of a projection region in which the reduced image is projected with the projection optical system is decentered from the optical axis with respect to the first direction.
 41. An exposure method of exposing a substrate to light from a pattern through liquid, the exposure method comprising: holding the substrate with a stage; projecting a reduced image of the pattern with the light onto the substrate through the liquid with a projection optical system; and driving the stage to perform a scanning exposure of the substrate so that the substrate is moved relative to the light with respect to a first direction perpendicular to an optical axis of the projection optical system, wherein the projection optical system comprises a refractive optical element having a light emitting surface, through a part of which the light passes in use and which is arranged nearest to an imaging plane of the projection optical system to contact the liquid in use, wherein the refractive optical element has a protruding portion formed in a light emitting side of the refractive optical element so as to protrude toward the imaging plane with respect to a surrounding portion other than the protruding portion, and wherein the protruding portion is formed so that a center of the light emitting surface is decentered from the optical axis with respect to the first direction.
 42. A projection optical system, which projects an image of a pattern arranged on a first plane onto a second plane with illumination light from the pattern, for use in an immersion exposure apparatus which exposes a substrate with the illumination light through the projection optical system and a liquid, the projection optical system comprising: a catadioptric arrangement of optical elements comprising a final lens arranged between the second plane and another optical element of the catadioptric arrangement of optical elements, a second plane side of the final lens has a light emitting surface a part of which the illumination light passes through, a downward-facing surface located above the light emitting surface, wherein the final lens is arranged so that the light emitting surface comes in contact with the liquid, at least the other optical element is arranged on an optical axis of the projection optical system, the image is projected in a projection region on the second plane, the projection region is off the optical axis with respect to a first direction perpendicular to the optical axis, and a center of the light emitting surface is away from the optical axis with respect to the first direction.
 43. The projection optical system according to claim 42, wherein the second plane side of the final lens has a side surface which extends upwardly and radially from the light emitting surface toward the downward-facing surface.
 44. The projection optical system according to claim 43, wherein the side surface is located between the light emitting surface and the downward-facing surface.
 45. The projection optical system according to claim 43, wherein the side surface is an inclined surface.
 46. The projection optical system according to claim 42, wherein the light emitting surface is substantially planar.
 47. The projection optical system according to claim 46, wherein a first plane side of the final lens has a convex surface.
 48. The projection optical system according to claim 42, wherein the second plane side of the final lens has a protruding portion which protrudes from the downward-facing surface, and the light emitting surface is located on the protruding portion.
 49. The projection optical system according to claim 48, wherein a width of the protruding portion with respect to the first direction is narrower than a width of the protruding portion with respect to a second direction perpendicular to the optical axis and the first direction.
 50. The projection optical system according to claim 49, wherein a scanning exposure is performed by the immersion exposure apparatus, and the substrate is moved to the first direction during the scanning exposure to a single shot region on the substrate.
 51. The projection optical system according to claim 49, wherein a width of the projection region with respect to the first direction is narrower than a width of the projection region with respect to the second direction.
 52. The projection optical system according to claim 49, wherein the light emitting surface is located nearest to the second plane in the final lens with respect to a direction of the optical axis.
 53. The projection optical system according to claim 42, wherein the center of the light emitting surface substantially matches the optical axis with respect to a second direction perpendicular to the optical axis and the first direction.
 54. The projection optical system according to claim 42, wherein a position of a center of the light emitting surface substantially matches a position of the center of the projection region with respect to the first direction and a second direction perpendicular to the optical axis and the first direction.
 55. The projection optical system according to claim 42, wherein a scanning exposure is performed by the immersion exposure apparatus, and the substrate is moved in the first direction during the scanning exposure to a single shot region on the substrate.
 56. The projection optical system according to claim 55, wherein a width of the projection region with respect to the first direction is narrower than a width of the projection region with respect to a second direction perpendicular to the optical axis and the first direction.
 57. The projection optical system according to claim 42, wherein the light emitting surface is located nearest to the second plane in the final lens with respect to a direction of the optical axis.
 58. An immersion exposure apparatus which exposes a substrate with light from the pattern via the liquid, the apparatus comprising: the projection optical system according to claim 42; and a liquid supply apparatus which is located around the light emitting surface of the final lens and includes a supply channel to supply the liquid under the light emitting surface, wherein the projection optical system projects the image of the pattern onto the substrate positioned under the final lens through the liquid supplied from the supply channel.
 59. An immersion exposure apparatus which exposes a substrate with an illumination light from a pattern through a liquid, the immersion exposure apparatus comprising: a projection optical system which projects an image of the pattern with the illumination light; a stage which holds the substrate; and a liquid supply apparatus that includes a supply channel to supply the liquid on the substrate held on the stage, wherein the projection optical system comprises: a catadioptric arrangement of optical elements comprising a final lens arranged between the second plane and another optical element of the catadioptric arrangement of optical elements, a second plane side of the final lens has a light emitting surface a part of which the illumination light passes through, and a downward-facing surface located above the light emitting surface, wherein the final lens is arranged so that the light emitting surface comes in contact with the liquid, at least the other optical element is arranged on an optical axis of the projection optical system, the image is projected in a projection region on the second plane, the projection region is off the optical axis with respect to a first direction perpendicular to the optical axis, and a center of the light emitting surface is away from the optical axis with respect to the first direction.
 60. A projection optical system, which projects an image of a pattern arranged on a first plane onto a second plane with illumination light from the pattern, for use in an immersion exposure apparatus which exposes a substrate with the illumination light through the projection optical system and a liquid, the projection optical system comprising: a catadioptric arrangement of optical elements comprising a final lens arranged between the second plane and another optical element of the catadioptric arrangement of optical elements, a second plane side of the final lens has a light emitting surface a part of which the illumination light passes through, and a downward-facing surface located above the light emitting surface, the final lens is arranged so that the light emitting surface comes in contact with the liquid, at least the other optical element is arranged on an optical axis of the projection optical system, the image is projected in a projection region on the second plane, the projection region is off the optical axis with respect to a first direction perpendicular to the optical axis, and a center of the light emitting surface is away from the optical axis with respect to the first direction.
 61. The projection optical system according to claim 60, wherein the second plane side of the final lens has a surface which extends upwardly and radially from the light emitting surface.
 62. The projection optical system according to claim 61, wherein the surface which extends upwardly and radially from the light emitting surface is located between the light emitting surface and a surface facing toward the second plane.
 63. The projection optical system according to claim 60, wherein the light emitting surface is substantially planar.
 64. The projection optical system according to claim 63, wherein a first plane side of the final lens has a convex surface.
 65. The projection optical system according to claim 60, wherein the downward-facing surface is substantially planar.
 66. The projection optical system according to claim 60, wherein the second plane side of the final lens has a protruding portion, and the light emitting surface is located on the protruding portion.
 67. The projection optical system according to claim 66, wherein a width of the protruding portion with respect to the first direction is narrower than a width of the protruding portion with respect to a second direction perpendicular to the optical axis and the first direction.
 68. The projection optical system according to claim 67, wherein a width of the projection region with respect to the first direction is narrower than a width of the projection region with respect to the second direction.
 69. The projection optical system according to claim 67, wherein the light emitting surface is located nearest to the second plane in the final lens with respect to a direction of the optical axis.
 70. The projection optical system according to claim 60, wherein the center of the light emitting surface substantially matches the optical axis with respect to a second direction perpendicular to the optical axis and the first direction.
 71. The projection optical system according to claim 60, wherein a position of a center of the light emitting surface substantially matches a position of the center of the projection region with respect to the first direction and a second direction perpendicular to the optical axis and the first direction.
 72. The projection optical system according to claim 60, wherein the light emitting surface crosses the optical axis.
 73. The projection optical system according to claim 60, wherein a width of the projection region with respect to the first direction is narrower than a width of the projection region with respect to a second direction perpendicular to the optical axis and the first direction.
 74. The projection optical system according to claim 60, wherein the light emitting surface is located nearest to the second plane in the final lens with respect to the first direction of the optical axis.
 75. An immersion exposure apparatus which exposes a substrate with light from the pattern via the liquid, the apparatus comprising: the projection optical system according to claim 60; and a liquid supply apparatus which is located around the light emitting surface of the final lens and includes a supply channel to supply the liquid under the light emitting surface, wherein the projection optical system projects the image of the pattern onto the substrate positioned under the final lens through the liquid supplied from the supply channel.
 76. An immersion exposure apparatus which exposes a substrate with an illumination light from a pattern through a liquid, the immersion exposure apparatus comprising: a projection optical system which projects an image of the pattern with the illumination light; a stage which holds the substrate; and a liquid supply apparatus that includes a supply channel to supply the liquid on the substrate held on the stage, wherein the projection optical system comprises: a catadioptric arrangement of optical elements comprising a final lens arranged between the second plane and another optical element of the catadioptric arrangement of optical elements, a second plane side of the final lens has: a light emitting surface a part of which the illumination light passes through, and a downward-facing surface located above the light emitting surface, the final lens is arranged so that the light emitting surface comes in contact with the liquid, at least the other optical element is arranged on an optical axis of the projection optical system, the image is projected in a projection region on the second plane, the projection region is off the optical axis with respect to a first direction perpendicular to the optical axis, and a center of the light emitting surface is away from the optical axis with respect to the first direction.
 77. A projection optical system, which projects an image of a pattern arranged on a first plane onto a second plane with illumination light from the pattern, for use in an immersion exposure apparatus which exposes a substrate with the illumination light through the projection optical system and a liquid, the projection optical system comprising: a catadioptric arrangement of optical elements comprising a final lens arranged between the second plane and another optical element of the catadioptric arrangement of optical elements, a second plane side of the final lens has a light emitting surface a part of which the illumination light passes through, the final lens is arranged so that the light emitting surface comes in contact with the liquid, the image is projected in a projection region on the second plane, the projection region is off an optical axis of the projection system with respect to a first direction perpendicular to the optical axis, and a center of the light emitting surface is away from the optical axis lens with respect to the first direction. 